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Roussin's red salt : ウィキペディア英語版
Roussin's red salt

Roussin’s Red Salt is the inorganic compound with the formula K2(). This metal nitrosyl was first described by Zacharie Roussin in 1858, making it the first synthetic iron-sulfur cluster.
==Structure and bonding==
Roussin's red salt anion is an edge-shared bitetrahedron, wherein a pair Fe(NO)2 units are bridged by a pair of sulfide ligands. The Fe-NO bonds are linear indicating NO is acting as a three electron donor. The diamagnetic compound obeys the 18-electron rule. The dark red colour of the complex is attributed to a number of charge-transfer interactions between the iron core and nitrosyl ligands.

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